The Buddypress-Ajax-Chat plugin by David Aubin will extend Buddypress to have an Ajax Chat client that works with Buddypress groups, as well as all WordPress users.
As of version 1.2.6 Buddypress Ajax Chat works with both WordPress MU and WordPress Single User. Now supports theme css.
Download: http://wordpress.org/extend/plugins/buddypress-ajax-chat/
Dynamic Endeavors also have other plugins:
Buddypress Extensions
Twire v 0.8
This plugin will extend Buddypress to have Twitter and BuddyPress combined to get a Twire.
You must have 2 things: 1. WordPress MU 2. Buddy Press
Twitter To Wire 1.4
This plugin allows your twitter posts to show up in your buddypress wire.
Premium Plugins
Dynamic Endeavors Premium is devoted to creating top notch plug-ins for WordPress MU and Buddypress.
More Info: http://dynamicendeavorsllc.com/plugins/
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Updated on 2010-8-17 to version 1.3.4